Rory McIlroy will get his 10th attempt to complete the career Grand Slam under way at 15:42 BST on Thursday when the Masters starts at Augusta National.
The Northern Irishman plays with the only man ranked higher than him in the world, 2022 victor Scottie Scheffler, and fellow American Xander Schauffele.
Spain’s defending champion Jon Rahm is out in the group before at 15:30, alongside England’s Matt Fitzpatrick.
Five-time winner Tiger Woods is among the later starters, going out at 18:24.
Record six-time winner Jack Nicklaus, three-time champion Gary Player and twice winner Tom Watson will hit the ceremonial opening tee shots before South Africa’s Erik Van Rooyen is first to tee off at 13:00 (08:00 local time).
The final group of 2020 Masters champion Dustin Johnson, 2021 Open winner Collin Morikawa and England’s Tommy Fleetwood will get under way six hours later.
Round one, Thursday, 11 April (all times BST)
13:00 Erik van Rooyen (SA), Jake Knapp (US)
13:12 Jose Maria Olazabal (Spa), Taylor Moore (US), Santiago de la Fuente (Mex)*
13:24 Danny Willett (Eng), Austin Eckroat (US), Stephan Jaeger (Ger)
13:36 Charl Schwartzel (SA), Luke List (US), Christo Lamprecht (SA)*
13:48 Gary Woodland (US), Thorbjorn Olesen (Den), Bryson DeChambeau (US)
14:00 Zach Johnson (US), Corey Conners (Can), Jasper Stubbs (Aus)*
14:12 Sergio Garcia (Spa), Chris Kirk (US), Ryan Fox (NZ)
14:24 Lucas Glover (US), Byeong Hun An (Kor), Harris English (US)
14:36 Phil Mickelson (US), Sepp Straka (Aut), Tony Finau (US)
14:48 Nick Taylor (Can), Joaquin Niemann (Chi), Russell Henley (US)
15:06 Patrick Cantlay (US), Min Woo Lee (Aus), Rickie Fowler (US)
15:18 Hideki Matsuyama (Jpn), Will Zalatoris (US), Justin Thomas (US)
15:30 Jon Rahm (Spa), Matt Fitzpatrick (Eng), Nick Dunlap (US)
15:42 Scottie Scheffler (US), Rory McIlroy (NI), Xander Schauffele (US)
15:54 Wyndham Clark (US), Viktor Hovland (Nor), Cameron Smith (Aus)
16:06 Lee Hodges (US), Adrian Meronk (Pol), Grayson Murray (US)
16:18 Camilo Villegas (Col), Denny McCarthy (US), Cameron Davis (Aus)
16:30 Mike Weir (Can), Ryo Hisatsune (Jpn), Neal Shipley (US)*
16:42 Vijay Singh (Fij), Si Woo Kim (Kor), Emiliano Grillo (Arg)
16:54 Fred Couples (US), Adam Hadwin (Can), Stewart Hagestad (US)*
17:12 Justin Rose (Eng), Eric Cole (US), Peter Malnati (US)
17:24 Akshay Bhatia (US), JT Poston (US), Shane Lowry (Ire)
17:36 Bubba Watson (US), Nicolai Hojgaard (Den), Adam Schenk (US)
17:48 Patrick Reed (US), Sung-jae Im (Kor), Kurt Kitayama (US)
18:00 Keegan Bradley (US), Matthieu Pavon (Fra), Tyrrell Hatton (Eng)
18:12 Adam Scott (Aus), Sam Burns (US), Cameron Young (US)
18:24 Tiger Woods (US), Jason Day (Aus), Max Homa (US)
18:36 Brian Harman (US), Brooks Koepka (US), Tom Kim (Kor)
18:48 Jordan Spieth (US), Ludvig Åberg (Swe), Sahith Theegala (US)
19:00 Dustin Johnson (US), Collin Morikawa (US), Tommy Fleetwood (Eng)
Round two, Friday, 12 April (all times BST)
13:00 Lee Hodges (US), Adrian Meronk (Pol), Grayson Murray (US)
13:12 Camilo Villegas (Col), Denny McCarthy (US), Cameron Davis (Aus)
13:24 Mike Weir (Can), Ryo Hisatsune (Jpn), Neal Shipley (US)*
13:36 Vijay Singh (Fij), Si Woo Kim (Kor), Emiliano Grillo (Arg)
13:48 Fred Couples (US), Adam Hadwin (Can), Stewart Hagestad (US)*
14:00 Justin Rose (Eng), Eric Cole (US), Peter Malnati (US)
14:12 Akshay Bhatia (US), JT Poston (US), Shane Lowry (Ire)
14:24 Bubba Watson (US), Nicolai Hojgaard (Den), Adam Schenk (US)
14:36 Patrick Reed (US), Sung-jae Im (Kor), Kurt Kitayama (US)
14:48 Keegan Bradley (US), Matthieu Pavon (Fra), Tyrrell Hatton (Eng)
15:06 Adam Scott (Aus), Sam Burns (US), Cameron Young (US)
15:18 Tiger Woods (US), Jason Day (Aus), Max Homa (US)
15:30 Brian Harman (US), Brooks Koepka (US), Tom Kim (Kor)
15:42 Jordan Spieth (US), Ludvig Åberg (Swe), Sahith Theegala (US)
15:54 Dustin Johnson (US), Collin Morikawa (US), Tommy Fleetwood (Eng)
16:06 Erik van Rooyen (SA), Jake Knapp (US)
16:18 Jose Maria Olazabal (Spa), Taylor Moore (US), Santiago de la Fuente (Mex)*
16:30 Danny Willett (Eng), Austin Eckroat (US), Stephan Jaeger (Ger)
16:42 Charl Schwartzel (SA), Luke List (US), Christo Lamprecht (SA)*
16:54 Gary Woodland (US), Thorbjorn Olesen (Den), Bryson DeChambeau (US)
17:12 Zach Johnson (US), Corey Conners (Can), Jasper Stubbs (Aus)*
17:24 Sergio Garcia (Spa), Chris Kirk (US), Ryan Fox (NZ)
17:36 Lucas Glover (US), Byeong Hun An (Kor), Harris English (US)
17:48 Phil Mickelson (US), Sepp Straka (Aut), Tony Finau (US)
18:00 Nick Taylor (Can), Joaquin Niemann (Chi), Russell Henley (US)
18:12 Patrick Cantlay (US), Min Woo Lee (Aus), Rickie Fowler (US)
18:24 Hideki Matsuyama (Jpn), Will Zalatoris (US), Justin Thomas (US)
18:36 Jon Rahm (Spa), Matt Fitzpatrick (Eng), Nick Dunlap (US)
18:48 Scottie Scheffler (US), Rory McIlroy (NI), Xander Schauffele (US)
19:00 Wyndham Clark (US), Viktor Hovland (Nor), Cameron Smith (Aus)
* denotes amateur
